A Theoretical Framework for the Electrochemical Characterization of Anisotropic Micro‐Emulsions**

نویسندگان

چکیده

Micro emulsions (MEs) offer an exceptionally broad spectrum of applications covering sensing, electrosynthesis, supercapacitors and redox-flow batteries. Herein, we develop the theory for a sophisticated electrochemical characterizion MEs with spatially time-invariant anisotropy in diffusion domain by means cyclic voltammerty (CV). By introducing dependent coefficients into Ficks' first law, derive modified equation to simulate any inherent ME under investigation. Moreover, formulating extended second-order homogeneous six-member square scheme kinetically controlled two-step two-electron reaction capture intricate entanglement chemical equilibria. Our theoretical concept is finally validated experimental CV data based redox methyl-viologen which paves way quantitative characterization MEs.

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ژورنال

عنوان ژورنال: ChemElectroChem

سال: 2021

ISSN: ['2196-0216']

DOI: https://doi.org/10.1002/celc.202100600